MATERIAL SAFETY DATA SHEET
EQUILON MSDS: 26412ET 01/04/99
URSA SUPER PLUS MOTOR OILS
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS:
EQUILON ENTERPRISES LLC
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
LEGEND:
N.D. - NOT DETERMINED N.A. - NOT APPLICABLE N.T- NOT TESTED
< - LESS THAN > - GREATER THAN
________________________________________________________________________________
1.NAME
________________________________________________________________________________
MATERIAL IDENTITY
Product Code and Name:
26412 URSA SUPER PLUS MOTOR OILS
Chemical Name and/or Family or Description:
Ursa Oils
This Material Safety Data Sheet may be used for the following products for
Hazard Communications purposes only; not intended to imply identical
performance/technical specifications:
02109 URSA SUPER PLUS SAE 15W-40 NF
02110 URSA SUPER PLUS SAE 10W
02111 URSA SUPER PLUS SAE 20-20W
02112 URSA SUPER PLUS SAE 30
02113 URSA SUPER PLUS SAE 40
02114 URSA SUPER PLUS SAE 50
02120 URSA SUPER PLUS SAE 10W-30 NF
_______________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
_______________________________________________________________________________
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS:
CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE
OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1.0 % OR
GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT
INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR
APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
OSHA IARC NTP OTHER NONE
X
_ _ _ _ _
Composition: (Sequence Number and Chemical Name)
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ____________
01 # Solvent-dewaxed heavy paraffinic petroleum 64742-65-0 65.00-79.99
distillates
02 # Hydrotreated heavy paraffinic petroleum 64742-54-7 10.00-19.99
distillates
03 # Solvent-refined heavy paraffinic petroleum 64741-88-4 3.00-9.99
distillates
04 # Solvent refined light paraffinic petroleum 64741-89-5 3.00-9.99
distillates or
05 Hydrotreated middle distillate 64742-46-7 3.00-9.99
06 # Modified polyolefin amide alkyleneamine 3.00-9.99
dispersant
07 * Zinc alkyl dithiophosphate 68649-42-3 1.00-2.99
PRODUCT IS NON-HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.
# COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA
BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL
MIST.
Exposure Limits referenced by Sequence Number in the Composition Section
Seq. Limit
____ _________________________________________________________________________
01 5 mg/m3 TWA-OSHA (MINERAL OIL MIST)
01 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST)
01 10 mg/m3 STEL ACGIH (MINERAL OIL MIST)
02 5 mg/m3 TWA-OSHA (MINERAL OIL MIST)
02 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST)
02 10 mg/m3 STEL ACGIH (MINERAL OIL MIST)
03 5 mg/m3 TWA-OSHA (MINERAL OIL MIST)
03 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST)
03 10 mg/m3 STEL ACGIH (MINERAL OIL MIST)
04 5 mg/m3 TWA-OSHA (MINERAL OIL MIST)
04 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST)
04 10 mg/m3 STEL ACGIH (MINERAL OIL MIST)
_______________________________________________________________________________
3. HAZARD IDENTIFICATION
_______________________________________________________________________________
EMERGENCY OVERVIEW
Appearance:
Bright and clear liquid
Odor:
Not determined
WARNING STATEMENT
_________________
WARNING ! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD
BASED ON ANIMAL DATA
HMIS NFPA
Health: 1 Reactivity: 0 Health: 1 Reactivity: 0
Flammability: 1 Special : - Flammability: 1 Special : -
POTENTIAL HEALTH EFFECTS
EYE SKIN INHALATION INGESTION
Primary Route of Exposure: X X X
_ _ _ _
EFFECTS OF OVEREXPOSURE
Acute:
Eyes:
May cause minimal irritation, experienced as temporary discomfort.
Skin:
Brief contact may cause slight irritation. Prolonged contact, as with
clothing wetted with material, may cause more severe irritation and dis-
comfort, seen as local redness and swelling.
Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Inhalation:
Vapors or mist, in excess of permissible concentrations, or in unusually
high concentrations generated from spraying, heating the material or as
from exposure in poorly ventilated areas or confined spaces, may cause
irritation of the nose and throat, headache, nausea, and drowsiness.
Ingestion:
If more than several mouthfuls are swallowed, abdominal discomfort, nausea,
and diarrhea may occur.
Sensitization Properties:
Unknown.
Chronic:
No adverse effects have been documented in humans as a result of chronic
exposure. Section 11 may contain applicable animal data.
Medical Conditions Aggravated by Exposure:
Because of its irritating properties, repeated skin contact may aggravate
an existing dermatitis (skin condition).
Other Remarks:
When overheated, product may release hydrogen sulfide (H2S) gas. H2S
concentrations above permissible concentrations can cause irritation of the
eyes and respiratory tract, headache, dizziness, nausea, vomiting,
diarrhea and pulmonary edema. At concentrations above 300 ppm, respiratory
paralysis, causing unconsciousness and death, can occur.
_______________________________________________________________________________
4. FIRST AID MEASURES
_______________________________________________________________________________
Eyes:
Flush eyes with plenty of water for several minutes. Get medical
attention if eye irritation persists.
Skin:
Wash skin with plenty of soap and water for several minutes. Get medical
attention if skin irritation develops or persists.
Ingestion:
If more than several mouthfuls of this material are swallowed, give two
glasses of water (16 oz.). Get medical attention.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air.
Get medical attention if breathing becomes difficult or respiratory
irritation persists.
Other Instructions:
Remove and dry-clean or launder clothing soaked or soiled with this
material before reuse. Dry cleaning of contaminated clothing may be
more effective than normal laundering. Inform individuals responsible for
cleaning of potential hazards associated with handling contaminated
clothing.
_______________________________________________________________________________
5. FIRE-FIGHTING MEASURES
_______________________________________________________________________________
Ignition Temperature - AIT (degrees F):
Not determined.
Flash Point (degrees F):
> 400 (COC)
Flammable Limits (%):
Lower: Not determined.
Upper: Not determined.
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam, or carbon dioxide to extinguish
flames. Use water spray to cool fire-exposed containers. Water or
foam may cause frothing.
Unusual or Explosive Hazards:
Hydrogen sulfide (H2S) may be released if overheated.
Extinguishing Media Which Must Not Be Used:
Not determined.
Special Protective Equipment for Firefighters:
Wear full protective clothing and positive pressure breathing apparatus.
_______________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
_______________________________________________________________________________
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal
protective equipment, including appropriate respiratory protection. Contain
spill if possible. Wipe up or absorb on suitable material and shovel up.
Prevent entry into sewers and waterways. Avoid contact with skin, eyes or
clothing.
If more than 840,265 pounds of product is spilled, then report spill
according to SARA 304 and/or CERCLA 102(a) requirements, unless product
qualifies for the petroleum exemption (CERCLA Section 101(14)).
_______________________________________________________________________________
7. HANDLING AND STORAGE
_______________________________________________________________________________
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained.
Storage:
Periods of exposure to high temperatures should be minimized. Water
contamination should be avoided.
_______________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
_______________________________________________________________________________
Protective Equipment (Type)
Eye/Face Protection:
Safety glasses, chemical type goggles, or face shield recommended to
prevent eye contact.
Skin Protection:
Workers should wash exposed skin several times daily with soap and water.
Soiled work clothing should be laundered or dry-cleaned.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If
vapor, mist or dust is generated and the occupational exposure limit of the
product, or any component of the product, is exceeded, use appropriate
NIOSH or MSHA approved air purifying or air supplied respirator after
determining the airborne concentration of the contaminant. Air supplied
respirators should always be worn when airborne concentration of the
contaminant or oxygen content is unknown.
Ventilation:
Adequate to meet component occupational exposure limits (see Section 2).
Exposure Limit for Total Product:
None established for product; refer to Section 2 for component
exposure limits.
_______________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
_______________________________________________________________________________
Appearance:
Bright and clear liquid
Odor:
Not determined
Boiling Point (degrees F):
Not determined.
Melting/Freezing point (degrees F):
Not applicable.
Specific Gravity (water=1):
.88 - .91
pH of undiluted product:
Not applicable.
Vapor Pressure:
Not determined.
Viscosity:
45.1 - 215 cSt at 40.0 C
VOC Content:
Not determined.
Vapor Density (air=1):
Not determined.
Solubility in Water (%):
Not determined.
Other: None
_______________________________________________________________________________
10. STABILITY AND REACTIVITY
_______________________________________________________________________________
This Material Reacts Violently With:
(If Others is checked below, see comments for details)
Air Water Heat Strong Oxidizers Others None of These
X
_ _ _ _ _ _
Comments:
Under extreme temperatures or extended storage periods, hydrogen sulfide
(H2S) gas may accumulate in the head-space of container.
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and
ketones, and combustion products or compounds of
sulfur (may include hydrogen sulfide).
Hazardous Polymerizations: DO NOT OCCUR
_______________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
_______________________________________________________________________________
TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA)
Median Lethal Dose
Oral:
LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Not determined.
Dermal:
LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic
Irritation Index, Estimation of Irritation (Species)
Skin:
(Draize) Believed to be > .50 - 3.00 /8.0 (rabbit) slightly irritating
Eyes:
(Draize) Believed to be < 15.00 /110 (rabbit) no appreciable effect
Sensitization:
Not determined.
Other:
Used gasoline motor oils have been shown to cause skin cancer when
repeatedly applied to mouse skin without any effort to remove the material
between applications. There is no evidence of a causal relationship between
skin cancer in humans and exposure to used motor oil.
_______________________________________________________________________________
12. DISPOSAL CONSIDERATIONS
_______________________________________________________________________________
Waste Disposal Methods
This product has been evaluated for RCRA characteristics and does not meet
the criteria of a hazardous waste if discarded in its purchased form.
Under RCRA, it is the responsibility of the user of the product to deter-
mine at the time of disposal, whether the product meets RCRA criteria for
hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may render the resulting materials hazardous.
Remarks
None
_______________________________________________________________________________
13. TRANSPORT INFORMATION
_______________________________________________________________________________
Transportation
DOT:
Proper Shipping Name:
Not regulated
IMDG:
Proper Shipping Name:
Not regulated
ICAO:
Proper Shipping Name:
Not regulated
TDG:
Proper Shipping Name:
Not regulated
_______________________________________________________________________________
14. REGULATORY INFORMATION
_______________________________________________________________________________
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ___________
None
Section 302/304 Extremely Hazardous Substances (CONT)
Seq. TPQ RQ
____ __________ __________
None
Section 311 Hazardous Categorization:
Acute Chronic Fire Pressure Reactive N/A
X
_ _ _ _ _ _
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
____________________________________________ ______________ _____________
Zinc alkyl dithiophosphate 68649-42-3 1.00-2.99
CERCLA 102(a)/DOT Hazardous Substances: (+ indicates DOT Hazardous Substance)
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ___________
01+ Naphthalene 91-20-3 0.01-0.09
02+ Cumene 98-82-8 0.01-0.09
03+ Styrene 100-42-5 0.01-0.09
04+ Ethylbenzene 100-41-4 0.01-0.09
CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's):
Seq. RQ
____ __________
01+ 100
02+ 5000
03+ 1000
04+ 1000
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the
Toxic Substance Control Act (TSCA) Chemical Substance Inventory.
Other:
None.
State Regulations:
California Proposition 65:
The following detectable components of this product are substances,
or belong to classes of substances, known to the State of California
to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
____________________________________________ ______________
None
International Regulations:
WHMIS Classification:
Not controlled
Canada Inventory Status:
Not determined.
EINECS Inventory Status:
Not determined.
Australia Inventory Status:
Not determined.
Japan Inventory Status:
Not determined.
_______________________________________________________________________________
15. ENVIRONMENTAL INFORMATION
_______________________________________________________________________________
Aquatic Toxicity:
Not determined.
Mobility:
Not determined.
Persistence and Biodegradability:
Not determined.
Potential to Bioaccumulate:
Not determined.
Remarks:
None
_______________________________________________________________________________
16. OTHER INFORMATION
_______________________________________________________________________________
None
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
Date: 1999-01-04 New X Revised, Supersedes: 1998-12-11
__________ _ _ __________
Inquiries regarding MSDS should be directed to:
Equiva Services LLC
Manager Product Stewardship
P.O. Box 674414
Houston, TX 77267-4414
_______________________________________________________________________________
17. PRODUCT LABEL Label Date: 1999-01-04
_______________________________________________________________________________
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS
LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS
AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT
OR OTHER RELATED REGULATORY REQUIREMENTS.
26412 URSA SUPER PLUS MOTOR OILS
WARNING STATEMENT
_________________
WARNING ! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD
BASED ON ANIMAL DATA
PRECAUTIONARY MEASURES
______________________
-Continuous contact with used gasoline motor oils has caused
skin cancer in laboratory animals.
-Avoid contact with used motor oil.
-Avoid prolonged breathing of vapor, mist, or gas.
-Clean oil-soaked clothing before reuse.
-Wash thoroughly after handling.
FIRST AID
_________
Eye Contact:
Flush eyes with plenty of water for several minutes. Get medical
attention if eye irritation persists.
Skin Contact:
Wash skin with plenty of soap and water for several minutes. Get medical
attention if skin irritation develops or persists.
Ingestion:
If more than several mouthfuls of this material are swallowed, give two
glasses of water (16 oz.). Get medical attention.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air.
Get medical attention if breathing becomes difficult or respiratory
irritation persists.
Note to Physician:
None
FIRE
____
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.
If more than 840,265 pounds of product is spilled, then report spill
according to SARA 304 and/or CERCLA 102(a) requirements, unless product
qualifies for the petroleum exemption (CERCLA Section 101(14)).
Chemical Name CAS Number Range in %
____________________________________________ _____________ ____________
# Solvent-dewaxed heavy paraffinic petroleum 64742-65-0 65.00-79.99
distillates
# Hydrotreated heavy paraffinic petroleum 64742-54-7 10.00-19.99
distillates
# Solvent-refined heavy paraffinic petroleum 64741-88-4 3.00-9.99
distillates
# Solvent refined light paraffinic petroleum 64741-89-5 3.00-9.99
distillates or
Hydrotreated middle distillate 64742-46-7 3.00-9.99
# Modified polyolefin amide alkyleneamine 3.00-9.99
dispersant
* Zinc alkyl dithiophosphate 68649-42-3 1.00-2.99
PRODUCT IS NON-HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.
# COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA
BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL
MIST.
Pennsylvania Special Hazardous Substance(s) CAS Number Range in %
____________________________________________ _____________ ____________
None
HMIS NFPA
Health: 1 Reactivity: 0 Health: 1 Reactivity: 0
Flammability: 1 Special : - Flammability: 1 Special : -
Transportation
DOT:
Proper Shipping Name:
Not regulated
CAUTION: Misuse of empty containers can be hazardous. Empty containers can
be hazardous if used to store toxic, flammable, or reactive
materials. Cutting or welding of empty containers might cause
fire, explosion or toxic fumes from residues. Do not pressurize
or expose to open flame or heat. Keep container closed and drum
bungs in place.
Name and Address:
Equilon Enterprises LLC
P.O. Box 674414
Houston ,TX 77267-4414
TRANSPORTATION EMERGENCY: (877)276-7283
CHEMTREC: (800)424-9300
HEALTH EMERGENCY: (877)276-7283
}