MATERIAL SAFETY DATA SHEET
EQUILON MSDS: 01518ET 01/04/99
CONCRETE FORM OIL VOC
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS:
EQUILON ENTERPRISES LLC
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
LEGEND:
N.D. - NOT DETERMINED N.A. - NOT APPLICABLE N.T- NOT TESTED
< - LESS THAN > - GREATER THAN
Name: CONCRETE FORM OIL VOC
Product Code: 01518
Date Issued: 1999-01-04 Supersedes: 1998-12-11
Company: EQUILON ENTERPRISES LLC
________________________________________________________________________________
1.NAME
________________________________________________________________________________
MATERIAL IDENTITY
Product Code and Name:
01518 CONCRETE FORM OIL VOC
Chemical Name and/or Family or Description:
Concrete Form Oil
_______________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
_______________________________________________________________________________
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS:
CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE
OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1.0 % OR
GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT
INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR
APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
OSHA IARC NTP OTHER NONE
X
_ _ _ _ _
Composition: (Sequence Number and Chemical Name)
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ____________
01 # Solvent-dewaxed heavy paraffinic petroleum 64742-65-0 65.00-79.99
distillates
02 * Kerosine, petroleum 8008-20-6 20.00-34.99
03 * Tall oil fatty acids 61790-12-3 3.00-9.99
PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.
# COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA
BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL
MIST.
Exposure Limits referenced by Sequence Number in the Composition Section
Seq. Limit
____ _________________________________________________________________________
01 5 mg/m3 TWA-OSHA (MINERAL OIL MIST)
01 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST)
01 10 mg/m3 STEL ACGIH (MINERAL OIL MIST)
02 100 ppm TWA-TEXACO
_______________________________________________________________________________
3. HAZARD IDENTIFICATION
_______________________________________________________________________________
EMERGENCY OVERVIEW
Appearance:
Light pale liquid
Odor:
Kerosine odor
WARNING STATEMENT
_________________
CAUTION ! MAY CAUSE DIZZINESS AND DROWSINESS
ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
HMIS NFPA
Health: 1 Reactivity: 0 Health: 1 Reactivity: 0
Flammability: 2 Special : - Flammability: 2 Special : -
POTENTIAL HEALTH EFFECTS
EYE SKIN INHALATION INGESTION
Primary Route of Exposure: X X X
_ _ _ _
EFFECTS OF OVEREXPOSURE
Acute:
Eyes:
May cause minimal irritation, experienced as temporary discomfort.
Skin:
Brief contact may cause slight irritation. Prolonged contact, as with
clothing wetted with material, may cause more severe irritation and dis-
comfort, seen as local redness and swelling.
Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Prolonged, widespread, or repeated skin contact may result in the
absorption of potentially harmful amounts of material.
Inhalation:
Vapors or mist, in excess of permissible concentrations, or in unusually
high concentrations generated from spraying, heating the material or as
from exposure in poorly ventilated areas or confined spaces, may cause
irritation of the nose and throat, headache, nausea, and drowsiness.
Inhalation may cause dizziness, drowsiness, euphoria, loss of coordination,
disorientation, headache, nausea, and vomiting. In poorly ventilated areas
or confined spaces, unconsciousness and asphyxiation may result. Prolonged
or repeated overexposure may result in the absorption of potentially
harmful amounts of material.
Ingestion:
If more than several mouthfuls are swallowed, abdominal discomfort, nausea,
and diarrhea may occur. Aspiration may occur during swallowing or vomiting
resulting in lung damage.
Sensitization Properties:
Unknown.
Chronic:
No adverse effects have been documented in humans as a result of chronic
exposure. Section 11 may contain applicable animal data.
Medical Conditions Aggravated by Exposure:
Because of its irritating properties, repeated skin contact may aggravate
an existing dermatitis (skin condition).
Other Remarks:
None
_______________________________________________________________________________
4. FIRST AID MEASURES
_______________________________________________________________________________
Eyes:
Flush eyes with plenty of water for several minutes. Get medical
attention if eye irritation persists.
Skin:
Wash skin with plenty of soap and water until all traces of material are
removed. Remove and clean contaminated clothing (See Other Instructions).
Destroy non-resistant footwear. Get medical attention if skin irritation
persists or contact has been prolonged.
Ingestion:
If person is conscious and can swallow, give two glasses of water (16 oz.)
but do not induce vomiting. If vomiting occurs, give fluids again. Have
medical personnel determine if evacuation of stomach or induction of
vomiting is necessary. Do not give anything by mouth to an unconscious or
convulsing person.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air.
Get medical attention if breathing becomes difficult or respiratory
irritation persists.
Other Instructions:
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
Remove and dry-clean or launder clothing soaked or soiled with this
material before reuse. Dry cleaning of contaminated clothing may be
more effective than normal laundering. Inform individuals responsible for
cleaning of potential hazards associated with handling contaminated
clothing.
_______________________________________________________________________________
5. FIRE-FIGHTING MEASURES
_______________________________________________________________________________
Ignition Temperature - AIT (degrees F):
Not determined.
Flash Point (degrees F):
120 (PMCC)
Flammable Limits (%):
Lower: Not determined.
Upper: Not determined.
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam or carbon dioxide to extinguish flames.
Use water spray to cool fire-exposed containers.
Unusual or Explosive Hazards:
None
Special Protective Equipment for Firefighters:
Wear full protective clothing and positive pressure breathing apparatus.
_______________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
_______________________________________________________________________________
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal
protective equipment, including appropriate respiratory protection. Contain
spill if possible. Wipe up or absorb on suitable material and shovel up.
Prevent entry into sewers and waterways. Avoid contact with skin, eyes or
clothing.
_______________________________________________________________________________
7. HANDLING AND STORAGE
_______________________________________________________________________________
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained.
Storage:
Store away from heat and open flame. Periods of exposure to high
temperatures should be minimized. Water contamination should be avoided.
_______________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
_______________________________________________________________________________
Protective Equipment (Type)
Eye/Face Protection:
Safety glasses, chemical type goggles, or face shield recommended to
prevent eye contact.
Skin Protection:
Protective clothing such as coveralls or lab coats should be worn. Launder
or dry-clean when soiled. Gloves and boots resistant to chemicals and
petroleum distillates required.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If
vapor, mist or dust is generated and the occupational exposure limit of the
product, or any component of the product, is exceeded, use appropriate
NIOSH or MSHA approved air purifying or air supplied respirator after
determining the airborne concentration of the contaminant. Air supplied
respirators should always be worn when airborne concentration of the
contaminant or oxygen content is unknown.
Ventilation:
Adequate to meet component occupational exposure limits (see Section 2).
Exposure Limit for Total Product:
None established for product; refer to Section 2 for component
exposure limits.
_______________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
_______________________________________________________________________________
Appearance:
Light pale liquid
Odor:
Kerosine odor
Boiling Point (degrees F):
Not determined.
Melting/Freezing point (degrees F):
Not applicable.
Specific Gravity (water=1):
.8463
pH of undiluted product:
Not applicable.
Vapor Pressure:
Not determined.
Viscosity:
7.7 cSt at 40.0 C
VOC Content:
Not determined.
Vapor Density (air=1):
Not determined.
Solubility in Water (%):
Not determined.
Other: None
_______________________________________________________________________________
10. STABILITY AND REACTIVITY
_______________________________________________________________________________
This Material Reacts Violently With:
(If Others is checked below, see comments for details)
Air Water Heat Strong Oxidizers Others None of These
X X
_ _ _ _ _ _
Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and
ketones.
Hazardous Polymerizations: DO NOT OCCUR
_______________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
_______________________________________________________________________________
TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA)
Median Lethal Dose
Oral:
LD50 Similar product > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Not determined.
Dermal:
LD50 Similar product > 2.00 g/kg (rabbit) practically non-toxic
Irritation Index, Estimation of Irritation (Species)
Skin:
(Draize) Similar product 2.42 /8.0 (rabbit) slightly irritating
Eyes:
(Draize) Similar product 4.70 /110 (rabbit) no appreciable effect
Sensitization:
Not determined.
Other:
Middle distillates have caused skin irritation and skin cancer in
laboratory animals when repeatedly applied and left in place between
applications. Studies to further evaluate the carcinogenic potential
of middle distillates are currently underway. Kidney damage has also been
observed in laboratory animals exposed to middle distillates.
_______________________________________________________________________________
12. DISPOSAL CONSIDERATIONS
_______________________________________________________________________________
Waste Disposal Methods
This product (as presently constituted) has the RCRA classification of
benzene toxicity and ignitability. If discarded in its present form, it
would have the hazardous waste numbers D018 and D001 respectively. Under
RCRA , it is the responsibility of the user of the product to determine ,
at the time of disposal, whether the product meets RCRA criteria for
hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may change the classification to non-hazardous, or
hazardous for reasons other than, or in addition to benzene toxicity and
ignitabilty.
Remarks
None
_______________________________________________________________________________
13. TRANSPORT INFORMATION
_______________________________________________________________________________
Transportation
DOT:
Proper Shipping Name:
Kerosene Mixture
Hazard Class:
3
Identification Number: UN 1223
Packing Group: III
Label Required:
Flammable liquid
IMDG:
Proper Shipping Name:
Kerosene Mixture
Hazard Class:
3.3
Identification Number: UN 1223
Packing Group: III
Label Required:
Flammable liquid
ICAO:
Proper Shipping Name:
Kerosene Mixture
Hazard Class:
3
Identification Number: UN 1223
Packing Group: III
Label Required:
Flammable liquid
TDG:
Proper Shipping Name:
Not evaluated
_______________________________________________________________________________
14. REGULATORY INFORMATION
_______________________________________________________________________________
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ___________
None
Section 302/304 Extremely Hazardous Substances (CONT)
Seq. TPQ RQ
____ __________ __________
None
Section 311 Hazardous Categorization:
Acute Chronic Fire Pressure Reactive N/A
X
_ _ _ _ _ _
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
____________________________________________ ______________ _____________
None
CERCLA 102(a)/DOT Hazardous Substances: (+ indicates DOT Hazardous Substance)
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ___________
None
CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's):
Seq. RQ
____ __________
None
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the
Toxic Substance Control Act (TSCA) Chemical Substance Inventory.
Other:
None.
State Regulations:
California Proposition 65:
The following detectable components of this product are substances,
or belong to classes of substances, known to the State of California
to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
____________________________________________ ______________
None
International Regulations:
WHMIS Classification:
Class B, Div 3: Combustible liquid
Canada Inventory Status:
This product, or its components, are listed on or are exempt from the
Canadian Domestic Substance List (DSL).
EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the
European Inventory of Existing Chemical Substances (EINECS) or the European
List of Notified Chemical Substances (ELINCS).
Australia Inventory Status:
This product, or its components, are listed on or are exempt from the
Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
Not determined.
_______________________________________________________________________________
15. ENVIRONMENTAL INFORMATION
_______________________________________________________________________________
Aquatic Toxicity:
LC50-96hr Aquatic toxicity rating is > 1000.00 mg/liter mysid shrimp (marine)
practically non-toxic
LC50-96hr Aquatic toxicity rating is > 1000.00 mg/liter (rainbow trout)
practically non-toxic
EC50-48hr Aquatic toxicity rating is > 1000.00 mg/liter (Daphnia magna)
practically non-toxic
EC50-96 hr Aquatic toxicity rating is = 2.40 mg/liter Selenastrum (cell
dens.) moderately toxic
LC50-96hr Aquatic toxicity rating is > 1000.00 mg/liter sheepshead
minnow(marine) practically non-toxic
Mobility:
Not determined.
Persistence and Biodegradability:
This product is reported to have a slow (< 30%) rate of biodegradation in a
test for ready biodegradation.
Potential to Bioaccumulate:
Not determined.
Remarks:
None
_______________________________________________________________________________
16. OTHER INFORMATION
_______________________________________________________________________________
It is recommended that all exposures to this product be minimized by
strictly adhering to recommended occupational controls procedures to avoid
any potential adverse health effects.
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
Date: 1999-01-04 New X Revised, Supersedes: 1998-12-11
__________ _ _ __________
Inquiries regarding MSDS should be directed to:
Equiva Services LLC
Manager Product Stewardship
P.O. Box 674414
Houston, TX 77267-4414
_______________________________________________________________________________
17. PRODUCT LABEL Label Date: 1999-01-04
_______________________________________________________________________________
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS
LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS
AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT
OR OTHER RELATED REGULATORY REQUIREMENTS.
01518 CONCRETE FORM OIL VOC
WARNING STATEMENT
_________________
CAUTION ! MAY CAUSE DIZZINESS AND DROWSINESS
ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
PRECAUTIONARY MEASURES
______________________
-Use only with adequate ventilation.
-Keep away from heat and flame.
-Avoid breathing vapor, mist, or gas.
-Keep container closed.
-Workers should wash exposed skin several times daily with
soap and water.
FIRST AID
_________
Eye Contact:
Flush eyes with plenty of water for several minutes. Get medical
attention if eye irritation persists.
Skin Contact:
Wash skin with plenty of soap and water until all traces of material are
removed. Remove and clean contaminated clothing (See Other Instructions).
Destroy non-resistant footwear. Get medical attention if skin irritation
persists or contact has been prolonged.
Ingestion:
If person is conscious and can swallow, give two glasses of water (16 oz.)
but do not induce vomiting. If vomiting occurs, give fluids again. Have
medical personnel determine if evacuation of stomach or induction of
vomiting is necessary. Do not give anything by mouth to an unconscious or
convulsing person.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air.
Get medical attention if breathing becomes difficult or respiratory
irritation persists.
Note to Physician:
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
FIRE
____
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.
Chemical Name CAS Number Range in %
____________________________________________ _____________ ____________
# Solvent-dewaxed heavy paraffinic petroleum 64742-65-0 65.00-79.99
distillates
* Kerosine, petroleum 8008-20-6 20.00-34.99
* Tall oil fatty acids 61790-12-3 3.00-9.99
PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.
# COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA
BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL
MIST.
Pennsylvania Special Hazardous Substance(s) CAS Number Range in %
____________________________________________ _____________ ____________
None
HMIS NFPA
Health: 1 Reactivity: 0 Health: 1 Reactivity: 0
Flammability: 2 Special : - Flammability: 2 Special : -
Transportation
DOT:
Proper Shipping Name:
Kerosene Mixture
Hazard Class:
3
Identification Number: UN 1223
Packing Group: III
Label Required:
Flammable liquid
CAUTION: Misuse of empty containers can be hazardous. Empty containers can
be hazardous if used to store toxic, flammable, or reactive
materials. Cutting or welding of empty containers might cause
fire, explosion or toxic fumes from residues. Do not pressurize
or expose to open flame or heat. Keep container closed and drum
bungs in place.
Name and Address:
Equilon Enterprises LLC
P.O. Box 674414
Houston ,TX 77267-4414
TRANSPORTATION EMERGENCY: (877)276-7283
CHEMTREC: (800)424-9300
HEALTH EMERGENCY: (877)276-7283
}