MATERIAL SAFETY DATA SHEET
MSDS Number: 400508ET - 0
24 Hour Emergency Assistance: CHEMTEL (877) 276-7283
General Assistance Number: (877) 276-7285
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SECTION 1 PRODUCT IDENTIFICATION
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MATERIAL IDENTITY: HAVOLINE® Motor Oil SAE 5W-20
PRODUCT CODES: 02197
COMPANY ADDRESS: Equilon Enterprises LLC, P. O. Box 4453, Houston, TX.
77210-4453
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SECTION 2 PRODUCT/INGREDIENTS
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CAS# CONCENTRATION INGREDIENTS
Mixture 100 %weight SAE 5W-20 Motor Oil
64742-54-7 80 - 89.99 %weight Solvent-refined, Hydrotreated heavy
paraffinic distillate
64742-52-5 5 - 14.99 %weight Hydrotreated heavy naphthenic
distillate
Proprietary 1 - 4.99 %weight Proprietary additives
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SECTION 3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Appearance & Odor: Bright and clear liquid. Petroleum oil odor
Health Hazards: No known immediate health hazards.
Physical Hazards: No known physical hazards.
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
Hazard Rating: Least - 0 Slight - 1 Moderate - 2 High - 3
Extreme - 4
Inhalation:
Inhalation of vapors (generated at high temperatures only) or oil mist may
cause mild irritation of the nose, throat, and respiratory tract.
Eye Irritation:
Lubricating oils are generally considered no more than minimally irritating to
the eyes.
Skin Contact:
Lubricating oils are generally considered no more than minimally irritating to
the skin. Prolonged and repeated contact may result in defatting and drying
of the skin that may cause various skin disorders such as dermatitis,
folliculitis or oil acne.
Ingestion:
Lubricating oils are generally no more than slightly toxic if swallowed.
Other Health Effects:
The International Agency for Research on Cancer (IARC) has determined there is
sufficient evidence for the carcinogenicity in experimental animals of used
gasoline motor oils. Handling procedures and safety precautions in the MSDS
should be followed to minimize exposure to the used product.
Material may release hydrogen sulfide (H2S), a highly toxic and extremely
flammable gas, when heated to 120 Degrees F or higher. H2S can cause
irritation of the eyes and respiratory tract, headache, dizziness, nausea,
vomitting, diarrhea, and pulmonary edema. At concentrations above 300 ppm,
respiratory paralysis, causing unconsciousness and death, can occur. The odor
("rotten egg") threshold is 0.02 ppm. Do not depend on sense of smell for
warning; H2S rapidly deadens the sense of smell.
Signs and Symptoms:
Irritation as noted above.
Aggravated Medical Conditions:
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure
to this product.
For additional health information, refer to section 11.
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SECTION 4 FIRST AID MEASURES
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Inhalation:
Remove victim to fresh air and provide oxygen if breathing is difficult. Get
medical attention.
Skin:
Remove contaminated clothing and shoes and wipe excess from skin. Flush skin
with water, then wash with soap and water. If irritation occurs, get medical
attention. Do not reuse clothing until cleaned.
Eye:
Flush with water. If irritation occurs, get medical attention.
Ingestion:
Do not induce vomiting. In general, no treatment is necessary unless large
quantities of product are ingested. However, get medical attention.
Note to Physician:
In general, emesis induction is unnecessary in high viscosity, low volatility
products such as oils and greases.
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SECTION 5 FIRE FIGHTING MEASURES
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Flash Point [Method]: >359 ºF/>181.67 ºC [ Cleveland Open Cup]
Extinguishing Media:
Material will float and can be re-ignited on surface of water. Use water fog,
'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do
not use a direct stream of water.
Fire Fighting Instructions:
Material will not burn unless preheated. Do not enter confined fire space
without full bunker gear (helmet with face shield, bunker coats, gloves and
rubber boots), including a positive pressure, NIOSH approved, self-contained
breathing apparatus.
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SECTION 6 ACCIDENTAL RELEASE MEASURES
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Protective Measures:
May burn although not readily ignitable.
Wear appropriate personal protective equipment when cleaning up spills. Refer
to Section 8.
Spill Management:
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or
other suitable material. Place in non-leaking container and seal tightly for
proper disposal.
Place in container for proper disposal.
Reporting:
CERCLA: Product is covered by EPA's Comprehensive Environmental Response,
Compensation and Liability Act (CERCLA) petroleum exclusion. Releases to air,
land, or water are not reportable under CERCLA (Superfund).
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water
Act (CWA). Spills into or leading to surface waters that cause a sheen must be
reported to the National Response Center, 1-800-424-8802.
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SECTION 7 HANDLING AND STORAGE
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Precautionary Measures:
Wash with soap and water before eating, drinking, smoking, applying cosmetics,
or using toilet. Launder contaminated clothing before reuse. Properly
dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. Avoid heat, open flames, including pilot lights, and strong
oxidizing agents. Use explosion-proof ventilation to prevent vapor
accumulation. Ground all handling equipment to prevent sparking.
Material may release hydrogen sulfide (H2S), a highly toxic and extremely
flammable gas, when heated to 120 Degrees F or higher. H2S may collect in the
headspace of the container.
Storage:
Store in a cool, dry place with adequate ventilation. Keep away from open
flames and high temperatures.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been
emptied, can contain explosive vapors. Do not cut, drill, grind, weld or
perform similar operations on or near containers.
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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Oil mist, mineral ACGIH TLV TWA: 5 mg/m3 STEL: 10 mg/m3
Oil mist, mineral OSHA PEL TWA: 5 mg/m3
Hydrogen sulfide ACGIH - TLV TWA: 10 ppmm STEL: 15 ppmm
Hydrogen sulfide OSHA - PEL_IS TWA: 10 ppmm STEL: 15 ppmm
Hydrogen sulfide Thermal > 120 degrees F.
EXPOSURE CONTROLS
Adequate ventilation to control airborne concentrations below the exposure
guidelines/limits.
PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential
exposure conditions such as handling practices, concentration and ventilation.
Information on the selection of eye, skin and respiratory protection for use
with this material is provided below.
Eye Protection:
Chemical Goggles, or Safety glasses with side shields
Skin Protection:
Use protective clothing which is chemically resistant to this material.
Selection of protective clothing depends on potential exposure conditions and
may include gloves, boots, suits and other items. The selection(s) should
take into account such factors as job task, type of exposure and durability
requirements.
Published literature, test data and/or glove and clothing manufacturers
indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, an approved respirator must be
worn. Respirator selection, use and maintenance should be in accordance with
the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Mist: Air Purifying, R or P style NIOSH approved respirator. For Vapors:
Air Purifying, R or P style prefilter & organic cartridge, NIOSH approved
respirator. Self-contained breathing apparatus.
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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Appearance & Odor: Bright and clear liquid. Petroleum oil odor
Substance Chemical Family: Lubricants
API Gravity: 34.5
Appearance: Bright and clear liquid.
Flash Point: > 359 ºF [Cleveland Open Cup]
Odor: Petroleum oil odor
Pour Point: -45 ºF - - -15 ºF
Specific Gravity: 0.856 - - 0.913
Viscosity: 48.5 cSt @ 40 ºC
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SECTION 10 REACTIVITY AND STABILITY
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Stability:
Material is stable under normal conditions.
Conditions to Avoid:
Avoid heat and open flames.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions.
A complex mixture of airborne solids, liquids and gases will evolve when this
material undergoes pyrolysis or combustion. Aldehydes, Calcium Oxide, Carbon
Monoxide, Carbon Dioxide, Hydrogen Sulfide, Ketones
and other unidentified organic compounds may be formed upon combustion.
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SECTION 11 TOXICOLOGICAL INFORMATION
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Acute Toxicity
Dermal LD50 >5.0 g/kg(Rabbit) OSHA: Non-Toxic
Based on components(s)
Eye Irritation Draize 0.67 / 110 [Rabbit, 24 HOUR(S)] OSHA:
Non-Irritating Based on components(s)
Oral LD50 >5.0 g/kg(Rat) OSHA: Non-Toxic
Based on components(s)
Skin Irritation Draize 0.27 / 8.0 [Rabbit, 24 HOUR(S)] OSHA:
Non-Irritating Based on components(s)
Carcinogenicity Classification
SAE 5W-20 Motor Oil
NTP: No IARC: Not Reviewed ACGIH: No OSHA: No
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SECTION 12 ECOLOGICAL INFORMATION
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Environmental Impact Summary:
There is no ecological data available for this product. However, this product
is an oil. It is persistent and does not readily biodegrade. However, it
does not bioaccumulate.
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SECTION 13 DISPOSAL CONSIDERATIONS
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RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine,
at the time of the disposal, whether the material meets RCRA criteria for
hazardous waste. This is because material uses, transformations, mixtures,
processes, etc. may affect the classification. Refer to the latest EPA, state
and local regulations regarding proper disposal.
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SECTION 14 TRANSPORT INFORMATION
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US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail
or highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
International Air Transport Association
Not regulated under IATA rules.
International Maritime Organization Classification
Not regulated under International Maritime Organization rules.
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SECTION 15 REGULATORY INFORMATION
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FEDERAL REGULATORY STATUS
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29
CFR 19.10.1200, because it carries the occupational exposure limit for mineral
oil mist.
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class
I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health:NO Delayed Health:NO Fire:NO Pressure:NO
Reactivity:NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
All component(s) of this material is(are) listed on the EPA/TSCA Inventory of
Chemical Substances.
Other Chemical Inventories:
Component(s) of this material is (are) listed on the Canadian DSL
State Regulation
This material is not regulated by California Prop 65, New Jersey Right-to-Know
Chemical List or Pennsylvania Right-To-Know Chemical List. However for
details on your regulation requirements you should contact the appropriate
agency in your state.
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SECTION 16 OTHER INFORMATION
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HMIS Rating (Health, Fire, Reactivity): 0, 1, 0
Revision#: 0
Revision Date: 11/09/2000
Revisions since last change (discussion): This Material Safety Data Sheet has
changed because Equiva Services LLC. has implemented new software to generate
the sheet. There will be slight differences in the hazard and precautionary
language as we incorporate the guidance contained in the ANSI MSDS standard
(ANSI Z400.1-1998). There are no significant changes to the health, safety or
precautionary messages. We encourage you to take the opportunity to reread
the sheet and review the information contained.
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SECTION 17 LABEL INFORMATION
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READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF
PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR
OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODES: 02197
HAVOLINE® Motor Oil SAE 5W-20
ATTENTION!
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE OIL ACNE OR DERMATITIS. USED
GASOLINE ENGINE OIL HAS BEEN SHOWN TO CAUSE CANCER IN LABORATORY ANIMALS.
Precautionary Measures:
Avoid prolonged or repeated contact with eyes, skin and clothing. Wash
thoroughly after handling.
FIRST AID
Inhalation: Remove victim to fresh air and provide oxygen if breathing is
difficult. Get medical attention.
Skin Contact: Remove contaminated clothing and shoes and wipe excess from
skin. Flush skin with water, then wash with soap and water. If irritation
occurs, get medical attention. Do not reuse clothing until cleaned.
Eye Contact: Flush with water. If irritation occurs, get medical attention.
Ingestion: Do not induce vomiting. In general, no treatment is necessary
unless large quantities of product are ingested. However, get medical
attention.
FIRE
In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon
dioxide (CO2) to extinguish flames. Do not use a direct stream of water.
Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or
other suitable material. Place in non-leaking container and seal tightly for
proper disposal.
CONTAINS: Solvent-refined, Hydrotreated heavy paraffinic distillate,
64742-54-7; Hydrotreated heavy naphthenic distillate, 64742-52-5; Proprietary
additives, Proprietary
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
HMIS Rating (Health, Fire, Reactivity): 0, 1, 0
TRANSPORTATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail
or highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
CAUTION: Misuse of empty containers can be hazardous. Empty containers can
be hazardous if used to store toxic, flammable, or reactive materials.
Cutting or welding of empty containers might cause fire, explosion or toxic
fumes from residues. Do not pressurize or expose to open flames or heat.
Keep container closed and drum bungs in place.
Name and Address
Equilon Enterprises LLC
P. O. Box 4453
Houston, TX 77210-4453
TRANSPORTATION EMERGENCY CHEMTEL (877) 276-7283
HEALTH EMERGENCY CHEMTEL (877) 276-7283
ADMINISTRATIVE INFORMATION
COMPANY ADDRESS: Equilon Enterprises LLC, P. O. Box 4453, Houston, TX.
77210-4453
Company Product Stewardship & Regulatory Compliance Contact: Ken Darmer
Phone Number: (281) 874-7982
MSDS FAX-BACK Phone Number: (877) 276-7285
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA,
IS THE PROPERTY OF EQUIVA SERVICES LLC AND IS NOT TO BE THE SUBJECT OF SALE OR
EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES LLC.
34390-11685-100R-2000-11-09 16:50:13