MATERIAL SAFETY DATA SHEET
Revision Date: 06/10/2004
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SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT: Shell SC-800 Liquid Asphalt
MSDS NUMBER: 53471E - 7
PRODUCT CODE(S): 50286
MANUFACTURER ADDRESS:Shell Oil Products US, P. O. Box 4453, Houston, TX.
77210-4453
TELEPHONE NUMBERS
Spill Information: (877) 242-7400
Health Information: (877) 504-9351
MSDS Assistance Number: (877) 276-7285
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SECTION 2 PRODUCT/INGREDIENTS
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CAS# CONCENTRATION INGREDIENTS
Mixture 100 %weight Shell SC-800 Liquid Asphalt
70592-78-8 40 - 99.99 %weight Vacuum Distillates
Mixture 0 - 59.99 %weight Vacuum Tower Bottoms
64741-53-3 0 - 39.99 %weight Heavy Naphthenic Petroleum Distillate
mixture 0 - 24.99 %weight Kerosene
64741-44-2 0 - 24.99 %weight Straight Run Middle Distillates
(petroleum)
7783-06-4 0 - 0.19 %weight Hydrogen Sulfide
NOTE: H2S is a naturally occuring constituent in the petroleum stream and is
not added separately to the product.
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SECTION 3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Appearance & Odor: Black viscous semi-solid. Asphalt or rotten egg odor.
Health Hazards: Hydrogen sulfide (H2S), an extremely flammable and toxic gas,
may be present. Contact with hot material will cause thermal burns. May
cause skin irritation. May cause cancer. May cause CNS depression.
NFPA Rating (Health, Fire, Reactivity): 1, 1, 0
Hazard Rating:Least - 0 Slight - 1 Moderate - 2 High - 3
Extreme - 4
Inhalation:
Hydrogen Sulfide (H2S) and other hazardous vapors may evolve and collect in
the headspace of storage tanks or other enclosed vessels. Hydrogen Sulfide is
an extremely flammable, toxic gas. Inhalation of vapors, mist or fumes
(generated at high temperatures) may cause irritation to the nose, throat and
respiratory tract. Breathing of high vapor concentrations may cause CNS
depression, evidenced by dizziness, light-headedness, headache, nausea,
drowsiness, and loss of coordination. Continued inhalation may result in
unconsciousness.
Eye Irritation:
Contact with hot material can cause thermal burns which may result in
permanent damage or blindness. Based on essentially similar product testing,
cool product is presumed to be minimally irritating to the eyes.
Skin Contact:
Contact with hot material can cause thermal burns which may result in
permanent damage. May be irritating to the skin causing a burning sensation,
redness and/or swelling. Other adverse effects not expected from brief skin
contact. Based on essentially similar product testing, cool product is
presumed to be minimally irritating to the skin.
Ingestion:
May be harmful if swallowed. Based on essentially similar product testing,
cool product is presumed to be no more than slightly toxic if ingested.
Generally considered to have a low order of acute oral toxicity.
Other Health Effects:
Carcinogenic in animal tests. Known human carcinogen. See Section 11.
Material may release hydrogen sulfide (H2S), a highly toxic and extremely
flammable gas, when heated to 180 Degrees F or higher. H2S can cause
irritation of the eyes and respiratory tract, headache, dizziness, nausea,
vomitting, diarrhea, and pulmonary edema. The odor ("rotten egg") threshold
is 0.02 ppm. Do not depend on sense of smell for warning; H2S rapidly
deadens the sense of smell.
Refer to Section 11, Toxicological Information, for specific information on
the following effects:
Genotoxicity
Primary Target Organs:
The following organs and/or organ systems may be damaged by overexposure to
this material and/or its components:
Kidney, Liver, Lungs
Signs and Symptoms:
Lung damage (scarring, bronchitis, emphysema) may be indicated by shortness of
breath, especially on exertion and may be accompanied by chronic cough.
Kidney damage may be indicated by changes in urine output or appearance, pain
upon urination or in the lower back or general edema (swelling from fluid
retention). Liver damage may be indicated by loss of appetite, jaundice
(yellowish skin and eye color), fatigue and sometimes pain and swelling in the
upper right abdomen.
For additional health information, refer to section 11.
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SECTION 4 FIRST AID MEASURES
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Inhalation:
Vaporization of H2S that has been trapped in clothing can be dangerous to
rescuers. Maintain respiratory protection to avoid contamination from victim
to rescuer. Mechanical ventilation should be used to resuscitate the victim.
DO NOT attempt to rescue victim unless proper respiratory protection is worn.
Move victim to fresh air and provide oxygen if breathing is difficult. Get
medical attention. If the victim has difficulty breathing or tightness of the
chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue
breathing or CPR as required and transport to the nearest medical facility.
Skin:
If contact with hot material, cool the burn area by flushing with large
amounts of water. Remove contaminated clothing. DO NOT attempt to remove
anything from the burn area or apply burn creams or ointments. If redness,
swelling, pain and/or blisters occur, transport to the nearest medical
facility for additional treatment. Cover the burn area loosely with a sterile
dressing, if available. Skin contact with hot product can produce thermal
burns. If the product has cooled and adhered to the skin, removal of the
product may be difficult without causing injury to burn area. Immediately
contact your physician for removal of product. Removal of the material should
be attempted only under the direction of a physician in order to prevent or
minimize potential injury to the affected area.
NOTE TO PHYSICIAN: If removal is attempted, mineral oil (not mineral spirits)
or a mineral oil based ointment may be applied to help soften the product to
facilitate removal.
Eye:
Flush eyes with plenty of water while holding eyelids open. Rest eyes for 30
minutes. If redness, burning, blurred vision or swelling occur, transport to
nearest medical facility for additional treatment.
Ingestion:
DO NOT induce vomiting. In general no treatment is necessary unless large
quantities are swallowed, however, get medical advice. Have victim rinse
mouth out with water, then drink sips of water to remove taste from mouth. If
vomiting occurs spontaneously, keep head below hips to prevent aspiration.
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SECTION 5 FIRE FIGHTING MEASURES
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Flash Point [Method]: 285 ºF/140.56 ºC [ Cleveland Open Cup]
Extinguishing Media:
Material will float and can be re-ignited on surface of water. Use water fog,
'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do
not use a direct stream of water.
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SECTION 6 ACCIDENTAL RELEASE MEASURES
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Protective Measures:
May burn although not readily ignitable.
Wear appropriate personal protective equipment when cleaning up spills. Refer
to Section 8.
Spill Management:
May burn although not readily ignitable. Use cautious judgement when cleaning
up large molten spills.
LARGE MOLTEN SPILL: Wear respirator and protective clothing as appropriate.
Shut off source of leak if safe to do so. Dike and contain. Allow product to
cool and remove as a solid.
SMALL MOLTEN SPILL: Allow product to cool and remove as a solid. Shut off
source of leak if safe to do so.
Reporting:
U.S. regulations require reporting releases of this material to the
environment which exceed the reportable quantity to the National Response
Center at (800)424-8802.
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water
Act (CWA). Spills into or leading to surface waters that cause a sheen must be
reported to the National Response Center, 1-800-424-8802.
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SECTION 7 HANDLING AND STORAGE
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Precautionary Measures:
Do not breathe material. Keep container closed. Use only with adequate
ventilation. Avoid heat, open flames, including pilot lights, and strong
oxidizing agents. Use explosion-proof ventilation to prevent vapor
accumulation. Ground all handling equipment to prevent sparking. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Material may release hydrogen sulfide (H2S), a highly toxic and extremely
flammable gas, when heated to 180 Degrees F or higher. H2S may collect in the
headspace of the container.
Handling:
Wash with soap and water before eating, drinking, smoking, applying cosmetics,
or using toilet. Launder contaminated clothing before reuse. Properly
dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. When asphaltic products are heated, they may give off small
amounts of hydrogen sulfide, an extremely flammable, highly toxic gas.
Breathing hydrogen sulfide must be avoided. Use ventilation, when possible,
or work upwind of source of vapors, fumes and mists. Do not allow molten
products to contact water or liquids as this can cause violent eruptions,
splatter hot material or ignite flammable materials.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been
emptied, can contain explosive vapors. Do not cut, drill, grind, weld or
perform similar operations on or near containers.
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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Asphalt fumes ACGIH TLV TWA: 0.5 mg/m3 Notation: A4 *,**
Kerosene ACGIH TLV TWA: 200 mg/m3
Kerosene OSHA PEL TWA: 100 ppmv
NOTE: * Asphalt (Petroleum; Bitumen) Fumes. As benzene-extractable inhalable
particulate (or equivalent Method).
** Not Classifiable as a Human Carcinogen-Asphalt Fume (coal tar-free).
Carbon monoxide OSHA - PEL TWA: 35 ppmv Ceiling: 200 ppmv
Hydrogen sulfide ACGIH - TLV TWA: 10 ppmm STEL: 15 ppmm
Hydrogen sulfide OSHA - PEL_IS TWA: 10 ppmm STEL: 15 ppmm
Hydrogen sulfide Thermal
EXPOSURE CONTROLS
Adequate ventilation to control airborne concentrations.
PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential
exposure conditions such as handling practices, concentration and ventilation.
Information on the selection of eye, skin and respiratory protection for use
with this material is provided below.
Eye Protection:
Chemical Goggles and Face Shield, or Safety Glasses
Skin Protection:
Use protective clothing which is chemically resistant to this material.
Selection of protective clothing depends on potential exposure conditions and
may include gloves, boots, suits and other items. The selection(s) should
take into account such factors as job task, type of exposure and durability
requirements.
Published literature, test data and/or glove and clothing manufacturers
indicate the best protection is provided by:
Clothing and gloves to protect against hot material.
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, an approved respirator must be
worn. Respirator selection, use and maintenance should be in accordance with
the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
Full-Face Air-Purifying Respirator for Acid Gases. Air-Purifying Respirator
for Organic Vapors. Self-contained breathing apparatus for use in
environments with unknown concentrations or emergency situations.
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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Appearance & Odor: Black viscous semi-solid. Asphalt or rotten egg odor.
Substance Chemical Family: Petroleum Hydrocarbon
Appearance: Black viscous semi-solid.
Flash Point: 285 ºF [Cleveland Open Cup]
Specific Gravity: 0.986 @ 60 ºF
Stability: Stable
Viscosity: 1200 cSt @ 140 ºF
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SECTION 10 REACTIVITY AND STABILITY
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Stability:
Material is stable under normal conditions.
Materials to Avoid:
Do not allow molten material to contact water or liquids as this can cause
violent eruptions, splatter hot material, or ignite flammable material. Avoid
contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions.
A complex mixture of airborne solids, liquids and gases will evolve when this
material undergoes pyrolysis or combustion. Carbon Monoxide, Hydrogen
Sulfide, Unidentified organic compounds
and other unidentified organic compounds may be formed upon combustion.
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SECTION 11 TOXICOLOGICAL INFORMATION
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Carcinogenicity:
Known human carcinogen. See Section 11.
Carcinogenicity Classification
Shell SC-800 Liquid Asphalt
NTP: No IARC: Not Classifiable (3) ACGIH: No OSHA: No
Heavy Naphthenic Petroleum Distillate
NTP: No IARC: Carcinogen (1) ACGIH: No OSHA: Yes
Vacuum Distillates
NTP: No IARC: Carcinogen (1) ACGIH: No OSHA: Yes
Carcinogenicity
Certain asphalt fume condensates have been shown to cause tumors when
repeatedly painted on the skin of laboratory mice. The relevance of these data
to humans exposed to the fume itself is unknown. The International Agency for
Research on Cancer has classified untreated mineral oils as Carcinogenic to
Humans (Group 1). Components used in this product (Vacuum Distillate, Heavy
Naphthenic Petroleum Distillate) meet the criteria for such oils. A similar
petroleum fraction also induced skin tumors in male mice in a long-term skin
painting study.
Epidemiology
There is no evidence that human exposure to bitumen or its fumes in
manufacturing processes or in road use results in any cancer risk. While there
is some evidence of an increased risk of lung cancer among roofers, building
insulators and mastic asphalt workers, concurrent or previous exposure to coal
tar products has also taken place and may therefore have been responsible.
Genotoxicity
Two samples of vacuum residuum were found to be non-genotoxic (no genetic
damage) in a live rat study and weakly genotoxic when metabolically activated
in an in vitro (test tube) assay. A kerosene-like material was found to be
mutagenic in the L5178Y mouse lymphoma assay with activation (a test-tube
procedure) and to cause chromosome damage in the in vivo (live animal) rat
cytogenetics assay. The majority of genotoxicity tests conducted on kerosene
and related petroleum streams have not indicated genotoxicity or mutagenicity.
Kidney
Nephropathy (kidney damage) caused by middle distillate inhalation appears to
be male rat specific (accumulation of alpha-2-u globulin) and is probably not
relevant to humans.
Liver
Tissue damage was observed in some organs of rabbits following repeated skin
exposure to a Middle Distillate petroleum stream. Microscopic changes seen in
the liver (mottled necrosis and centrilobular degeneration), kidney and
bladder (hyperplasia) were considered to be secondary to (caused by) the
severe skin irritancy.
Lungs
Mice exposed to laboratory-generated asphalt fume for up to 21 months
developed bronchitis along with inflammation and other signs of lung injury.
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SECTION 12 ECOLOGICAL INFORMATION
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Environmental Impact Summary:
There is no ecological data available for this product.
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SECTION 13 DISPOSAL CONSIDERATIONS
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RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine,
at the time of the disposal, whether the material meets RCRA criteria for
hazardous waste. This is because material uses, transformations, mixtures,
processes, etc. may affect the classification. Refer to the latest EPA, state
and local regulations regarding proper disposal.
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SECTION 14 TRANSPORT INFORMATION
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US Department of Transportation Classification
Proper Shipping Name: Elevated temperature liquid, N.O.S. (Petroleum Asphalt)
Identification Number: UN3257
Hazard Class/Division: 9 (Miscellaneous)
Packing Group: III
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or
highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
Emergency Response Guide # 128
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SECTION 15 REGULATORY INFORMATION
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FEDERAL REGULATORY STATUS
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class
I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
SARA Extremely Hazardous Substances (302/304):
Residues, Petroleum, Vacuum RQ 100 lbs Reportable Spill => 167 lbs or 20
gal
SARA Hazard Categories (311/312):
Immediate Health:YES Delayed Health:YES Fire:NO Pressure:NO
Reactivity:NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
This material is listed on the EPA/TSCA Inventory of Chemical Substances.
Other Chemical Inventories:
Australian AICS, Canadian DSL, European EINECS, Korean Inventory,
State Regulation
The following chemicals are specifically listed by individual states; other
product specific health and safety data in other sections of the MSDS may also
be applicable for state requirements. For details on your regulatory
requirements you should contact the appropriate agency in your state.
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65).
WARNING: This product contains a chemical(s) known to the State of California
to cause cancer.
WARNING: This product contains a chemical(s) known to the State of California
to cause birth defects or other reproductive harm.
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SECTION 16 OTHER INFORMATION
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Revision#: 7
Revision Date: 06/10/2004
Revisions since last change (discussion): This Material Safety Data Sheet
(MSDS) has been newly reviewed to fully comply with the guidance contained in
the ANSI MSDS standard (ANSI Z400.1-1998). We encourage you to take the
opportunity to read the MSDS and review the information contained therein.
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SECTION 17 LABEL INFORMATION
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READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF
PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR
OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODE(S): 50286
Shell SC-800 Liquid Asphalt
CAUTION!
The following organs and/or organ systems may be damaged by overexposure to
this material and/or its components. CONTACT WITH HOT PRODUCT CAN CAUSE
THERMAL BURNS.
OVEREXPOSURE TO VAPORS CAN CAUSE CNS DEPRESSION. MAY CAUSE SKIN IRRITATION.
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE OIL ACNE OR DERMATITIS.
MATERIAL AND/OR COMPONENTS THAT HAVE BEEN SHOWN TO CAUSE CANCER INCLUDE: Heavy
Naphthenic Petroleum Distillate,Heavy Naphthenic Petroleum Distillate,Vacuum
Distillates,Vacuum Distillates
MAY CAUSE DAMAGE TO: Kidney, Liver, Lungs
Refer to Section 11, Toxicological Information, for specific information on
the following effects:
Genotoxicity
Precautionary Measures:
Hydrogen Sulfide and other hazardous vapors may evolve and collect in the
headspace of storage tanks or other enclosed vessels. Hydrogen Sulfide is an
extremely flammable, toxic gas. Respiratory protection should be worn when
venting tanks. Avoid prolonged or repeated contact with eyes, skin and
clothing. Avoid contact with hot material. Avoid contact with water or
liquids. Avoid breathing of vapors, fumes, or mist. Use only with adequate
ventilation. Avoid contact with eyes, skin and clothing. Keep container
closed when not in use. Wash thoroughly after handling.
FIRST AID
Inhalation: Move victim to fresh air and provide oxygen if breathing is
difficult. Get medical attention. DO NOT attempt to rescue victim unless
proper respiratory protection is worn. Vaporization of H2S that has been
trapped in clothing can be dangerous to rescuers. Maintain respiratory
protection to avoid contamination from victim to rescuer. Mechanical
ventilation should be used to resuscitate the victim. If the victim has
difficulty breathing or tightness of the chest, is dizzy, vomiting or
unresponsive, give 100% oxygen with rescue breathing or CPR as required and
transport to the nearest medical facility.
Skin Contact: If contact with hot material, cool the burn area by flushing
with large amounts of water. Remove contaminated clothing. DO NOT attempt to
remove anything from the burn area or apply burn creams or ointments. Flush
exposed area with water and follow by washing with soap if available. If
redness, swelling, pain and/or blisters occur, transport to the nearest
medical facility for additional treatment. If skin irritation persists after
washing, get medical advice. Cover the burn area loosely with a sterile
dressing, if available.
Eye Contact: Flush eyes with plenty of water while holding eyelids open.
Rest eyes for 30 minutes. If redness, burning, blurred vision or swelling
occur, transport to nearest medical facility for additional treatment.
Transport to nearest medical facility for additional treatment.
Ingestion: DO NOT induce vomiting. If vomiting occurs spontaneously, keep
head below hips to prevent aspiration. Have victim rinse mouth out with
water, then drink sips of water to remove taste from mouth. In general no
treatment is necessary unless large quantities are swallowed, however, get
medical advice.
FIRE
In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon
dioxide (CO2) to extinguish flames. Do not use a direct stream of water.
Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
May burn although not readily ignitable. Use cautious judgement when cleaning
up large molten spills.
LARGE MOLTEN SPILL: Wear respirator and protective clothing as appropriate.
Shut off source of leak if safe to do so. Dike and contain. Allow product to
cool and remove as a solid.
SMALL MOLTEN SPILL: Allow product to cool and remove as a solid.
CONTAINS: Vacuum Distillates, 70592-78-8; Vacuum Tower Bottoms, Mixture; Heavy
Naphthenic Petroleum Distillate, 64741-53-3; Kerosene, mixture; Straight Run
Middle Distillates (petroleum), 64741-44-2; Hydrogen Sulfide, 7783-06-4
NFPA Rating (Health, Fire, Reactivity): 1, 1, 0
TRANSPORTATION
US Department of Transportation Classification
Proper Shipping Name: Elevated temperature liquid, N.O.S. (Petroleum Asphalt)
Identification Number: UN3257
Hazard Class/Division: 9 (Miscellaneous)
Packing Group: III
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or
highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
Emergency Response Guide # 128
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65).
WARNING: This product contains a chemical(s) known to the State of California
to cause cancer.
WARNING: This product contains a chemical(s) known to the State of California
to cause birth defects or other reproductive harm.
CAUTION: Misuse of empty containers can be hazardous. Empty containers can
be hazardous if used to store toxic, flammable, or reactive materials.
Cutting or welding of empty containers might cause fire, explosion or toxic
fumes from residues. Do not pressurize or expose to open flames or heat.
Keep container closed and drum bungs in place.
Name and Address
Shell Oil Products US
P. O. Box 4453
Houston, TX 77210-4453
ADMINISTRATIVE INFORMATION
MANUFACTURER ADDRESS: Shell Oil Products US, P. O. Box 4453, Houston, TX.
77210-4453
Company Product Stewardship & Regulatory Compliance Contact: Barbara Schroeder
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA,
IS THE PROPERTY OF SHELL OIL PRODUCTS US AND IS NOT TO BE THE SUBJECT OF SALE
OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SHELL OIL PRODUCTS US.
43639-12002-100R-09/02/2004